The primary goal of this book is to summarize the current level of accumulated knowledge about the physical structure of solid surfaces with emphasis on well-defined surfaces at the gas-solid and vacuum-solid interfaces.

The intention is not only to provide a standard reference for practitioners, but also to provide a good starting point for scientists who are just entering the field. The presentation in most of the chapters therefore assumes that the typical reader will have a good undergraduate background in chemistry, physics, or materials science. At the same time, coverage is comprehensive and at a high technical level with emphasis on fundamental physical principles. This first volume in a new series is appropriately devoted to the physical structure of surfaces, knowledge of which will be essential for a complete understanding of electronic properties and dynamical processes, the topics of the next two volumes in the series.

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